Here is what you need to know. They put two batteries in there in parallel, because one can often not deliver enough current to spin the motor.
As the load increases, the internal resistance in the battery is such that the output voltage drops.
The funny thing about a starter motor, is that it will try to do its required amount of work.
For instance, say it takes 4800 watts of work to spin a motor. Watts is Volts times Amps.
If you supply that motor with 12 volts, it will draw 400 amps.
If you let the voltage drop to 6 volts, it will draw 800 amps.
When you try to jump it off with one battery, it cannot supply the amps needed at 12 volts. So, the voltage drops, the current goes up, until it reaches the max the battery can supply.
Which is enough to melt the starter wire.
The best way to jump it off?
Charge the batteries and put them back in.
Next best way?
A big battery, and really big jumper cables. Bigger than what you use to jump a car.