Fill it (cold) until it won't take anymore. Start truck with cap off. Add coolant as needed. Install cap. Make sure overflow has at least some coolant in it. Let truck warm up, then shut it off. Let it get cold again, now check radiator and overflow levels. If necessary top radiator off, and the reservoir, done.
Radiator cap vents coolant (as it expands) AND air into the overflow, and as long as there is coolant in the overflow, can only draw coolant back in to replenish the radiator.