If the bleeder screws had a rubber cap over the end of them,that will increase your chances of success getting them to unscrew without breaking off..
If they didn't have a cap over them,I'd use a tiny drill bit to ream out any rust and dirt from the bleeder hole and squirt some penetrating oil in there with the spray nozzle straw,and heat up the caliper or wheel cylinder with a torch briefly around the screw ,if your lucky they will come loose without breaking..then you may have to finish cleaning the bleed hole out or replace them (best option) so the brakes can be bled..
Some brake fluid turns dark as it ages too,so it may not be moisture,but chances are its due for a flushing anyways,if its been in there more than 3 years..up here brake lines rot and pop about that often,so most vehicles have relatively "fresh" fluid in them..