The 14b will be an increase in strength the d44 will not increase your axle strength over the 10b you have now. But the the fact it’s 8lug and the ratio matches the rear is the bonus. That saves a lot of bs swapping the 8 lug parts from the knuckles out. If you intend to wheel the K5 with that big block an investment in chrome-moly front axle shafts would be smart. Though if you keep the front diff open the stock shafts may survive for a little while.
The size of the 14b being larger in every direction will effect your driveshaft length. If you compare the distance from the axle centerline to the pinion yoke to your 10 bolt and the 14b you’ll find the 14b yoke is further forward. That will reduce your driveshaft length. Factor in a 208 tcase with a slip yoke output and you may find the stock shaft has the slip bottomed out in the tcase or really close. Adding a lift might extend the length slightly but the angles will be way off.
So while the 3/4 ton 14b is a bolt in affair you may have to make some adjustments to deal with these other issues.
In my case with a ‘91 k5, 14b 4” lift with a shackle flip out back I had to make many adjustments. First the pinion angle with the shackle flip was garbage. Chucked the rear u-joint within the first 20 miles having it together. After a ton of research I chose to go to a cv (double carden) rear shaft. I kept the slip yoke in the 241 and the custom shaft I had built with a bolt on slip shaft to mimic the stock shaft and avoid having to move to a sye. The cv shaft required a major pinion angle change. I had to move it 8 degrees up so the shaft and pinion angle matched (per multiple guides online like Tom Woods).
As many changes spur further changes that increased pinion angle rotated the drive mr side shock mount down so much I couldn’t bolt in a standard shock because the can hit the housing before you could get the bolt in for the shock on the mount.
I ended up getting new lower shock mounts from ruff stuff, cutting the old off and welding the new on for a better angle.
Using the pinion angle shim works but isn’t ideal. Hindsight being what it is, I should have just got new spring mounts and burned them it at the right angle. Again, either way works but not having the shims to possibly wiggle out is a little more secure.