When I cc'd the head on my inline 6, all I did was take a piece of plexi-glass big enough to cover the combustion chamber, drill two holes in it (one to fill and one to bleed air out). I put some grease around the outer edges of the plexi-glass to seal, then with a graduated cylinder or syringe, measured how much tranny fluid I could put in the combustion chamber. Of course you will want to now how much in cc's, mine measured 52cc's each (it was a small 200 inline six, ford). There is a formula to figure compression from knowing what cc's your combustion chambers are, and bore, stroke, etc...
Just to add, not being rude, but it's "mill" the head and "deck" the block, and it is best if you do these together, just don't do one or the other.
Kirk