yeah, you'll wanna get into that factory finish some.. catalyst will more than likely eat into the air-dried enamel...
properly done, you can just put catalyzed paint over the factory paint and get away with it... primer or a sealer is nice, but I've done it over properly prepped factory finishes, and been fine... I try not to, but it has happened..
but paint will be anywhere from $100 to $400 depending on what paint..
whereas, a gal of rusto is like, $75... you could probably get away with just douching over the rattlecan with a thinned rusto and not have it freak out..
but more importantly than that, the ****tier you prep, leaving paint edges, lot's of featheredge cuts, etc, your WAY more likely to have issues...
in other words, kind of figure a good even cut to it all... the rattlecan should come off pretty easy.. just get it into the factory paint a bit, just so everythings been hit, no shine.. use course scuffpads for all the joints, etc.. makes it go quicker.. and you can do a bunch with a electric palm sander and some effort.. granted, a DA kills it.. but it's doable...

Ryoken's bodywork message of the day...

and

shine is the debil!
your paint is only as good as the surface below it...
make sure you get about 10% to 15% reducer in at a minimum.. helps it flow a bit.. I usually like to see a 6 count drip or so off the mixing stick for sprayed rusto...
you want it thick enough that it sprays ok thru a gun, and just leaves a bit of orange peel after a couple coats... not balls flat, and not a Sunkist..
depending on color change and how thin you mix it, you could be putting on anywhere from 2, to 5, 6 coats...