If it barely passed the test you should probably start with an engine tuneup, check the compression, etc. You can't make a worn out engine perform much better if it needs a rebuild. That said there are lots of emissions legal stuff - headers, cams, intakes just like pre emission days (remember?)
If you dont mind spending 300-400 on tools you can reprogram your computer for better performance without touching the engine. If you do modify the engine you'll want to burn/buy a new chip anyway.
http://www.mindspring.com/~amattei/akmelect.htm
Before I found these sites you couldn't have given me a computer. Now I love EFI :-)