Your sure it is the P/S belt that squeals ?...it might be the alternator belt..tried running it with the P/S belt off to make sure?..
Some belts do work better than others--I am not a big fan of those "cogged" v-belts that have the cogs on the inner part of the "V",they only work better than a regular V belt on applications with a small pulley ,the cogs let it wrap around the smaller sheave better...
I have substituted a 3/8" kevlar corded belt intended for lawn & garden or industrial applications that have a rather rough textured canvas like cover on the belt,for the alternator on one of my 6.2 diesels.
That had a belt that squealed like a stuck pig until it had been run a good 10 minutes with a Gates v belt on it (that looks new too!)--it ran silent with the Kevlar one,and I noticed the volt meter showed a charge higher right away,while the Gates wouldn't let the needle move till it stopped squealing..
I assumed there was a heavy load on the alternator till the fast idle cold advance shut off and the battery regained what it lost from long cranking to start it cold,because the belt squeal would just stop "instantly" when the fast idle shut off..
Unfortunately the 3/8" belt was only a decent fit in the alternator sheave,it sat too low in the crank pulley and "hit bottom"on it, and it soon wore thin, and failed...but it was QUIET !..
I then tried using a 1/2" wide kevlar belt ,but it was too fat to fit good in the alternator pulley,it stuck up above the pulley a bit, and it cut a groove in each side of the belt..and came apart..
Automotive belts are usually 7/16" wide (or 15/32") with a slightly different taper to the wedge..and are made of rubber and fabric not as tough as kevlar belts..if I could find a pulley for the alternator thats wider,the 1/2" kevlar belt would likely work great..(I have seen some on bigger trucks and industrial applications)..
Dayco sells belts that are "gold label" for truck applications that are 17/32" wide ,instead of 15/32" wide...those will work on "most" stock pulleys,but not all--the "17" series are listed for "heavy duty" applications where the "15" series are the "regular" stock OEM sized belts..example, a Dayco belt for a stock OEM replacement would have a number beginning with 15,like a 15445 ,the heavier "17" series equivalent would be a 17445...you'd have to make sure that one would fit all the sheaves properly..
The belt shouldn't have to be too tight not to slip--too much tension on it will chow the bearings in no time..most power steering pumps ,if the belt is to loose,will cause "jerky" steering at the wheel with intermittent squeals..if it squeals constantly,something else might be wrong,like a restriction in the hoses ,causing the pump to work real hard--
(A crude test for a P/S pump to see if its putting out decent pressure is to crimp the pressure hose shut for a few seconds,the belt should squeal instantly if its ok )..or perhaps the pulley is slipping on the pump shaft--it is only a light press fit..that might make a squeal similar to a slipping belt...
I see newer vehicles with plastic P/S pulleys,and cant see how they hold up at all..they are pretty fragile..