I just did a cursory search online, and couldn't find any info on Vortec motor piston design.
I doubt the Vortec pistons have any differences than any other basic flat top or dished piston, if I remember correctly, a flat top piston is (at this point in time) optimum for combustion efficiency, with the cylinder head design being where changes should be made. Flame front and propagation are the problems you run into when you start messing with the piston design,(such as domes, or anything that blocks flame travel or disturbs airflow) but in some cases, to achieve a lot of compression, you don't have much choice.
It's my understanding that the Vortecs are so good because GM A)did an extremely good job casting them (my casting ARE smooth) B) the combustion chamber is awesome and C) the ports are also well designed. I'd imagine at this point in time, GM has figured out how to get higher compression, better, cleaner burn, and whatever flow characteristics (swirl, etc) necessary to make power, all in one set of heads, whereas in the 80's, it was all about restrictive ports that promoted velocity and swirl solely, with outdated combustion chamber design.
Since these are 64 CC heads, the Vortec swap is really no different compression wise than going with any other SBC 64CC head. I believe 10CC's is equal to approx. 1 point of compression in a 350, so if you are starting out with a 76CC chamber and 8-8.2:1 compression(such as a lot of 70's and 80's 350's) you should still be safe with the Vortecs, as the combustion chamber design lends itself to higher compression without detonation, which means higher octane gas isn't needed.
Of course, if you already have 8.8:1 or something with 76CC heads, and swap 64CC heads, you'll end up having to run mid grade or premium.
If I were doing the swap (and I am) I would make certain that the compression I was running to start with, won't exceed what I could run on 87 octane. (which I have) In my case though, I was able to verify the CR via the piston maker, since I am building the engine from scratch, whereas someone that is interested in swapping heads alone, would need to be more careful, and do some careful calculating.