If it's loosening up, somethings not right. Belt should break before you ever have to worry about the pump working itself loose. In ther words, just figure out why it's loosening up and fix that, no need for a second belt.
You'd need a complete pulley setup off of a donor vehicle to get them to line up likely, and power steering pulley is a pain to get off, need to get the puller to remove it. I had to deal with pulleys off of multiple vehicles putting my truck together...it's a major hassle. All sorts of different pulley combinations used, and that means that not all pulleys will line up with each other.