Well thats the thing...in adjustable TPS', GM stated .54+/- at idle, but since we are saying that the TBI TPS is non-adjustable, the ECM sends a reference voltage, and calculates off of startup TPS voltage, if 5V is the reference, and it sees .5V(10%) on startup then .5V becomes idle TPS value, or 0% throttle. Everything off of that, say 1V, would be calculated to arrive at the corresponding throttle opening. So the ECM in this case would then "know" that 1V=20% throttle opening.
Assuming we've determined its operation correctly (which begs the question why people would bother modifying the non-adjustable mounting) things like power enrichment (pump shot for a carb) would simply be based off of throttle %, not voltage.
Again, all this hinges on whether or not the TPS "output" to the ECM is smooth and consistent, and has no electrical dead spots in it's travel. Yes, that's voltage, but not important the way it would be if the ECM were expecting X voltage at Y throttle opening.