GM had a service bulletin out in the early 80's to paint the case if there was a porosity problem, can't remember what type of paint it was though, some special GM number made by somebody else though.
Bare aluminum is a great heat conductor, but black works well too. And if you have a good cooler it don't really matter if you do or don't.
Deburring the case is a good idea to prevent stress risers which can lead to a crack, but it takes away a slight amount of cooling ability from the case...all those little risers are like heat sinks to get rid of the heat in the case.