Well I just hooked up the S terminal to the positive on the battery and the solenoid is clicking. I also hooked up the aux battery and its working the same. When I switch it on should an multimeter show the additional amps?
Basically, no. At least as I read what you asked.
When you hook up the S terminal to either battery, the solenoid should pull in, as long as they both share a ground terminal.
If each battery is hooked to each big lug, then when you power up the solenoid, the two will be hooked in parallel. Since you need a voltage difference to create a current, then you will see very little current flow.
Its very unlikely that both batteries will be in the exact same state of charge and condition, so there will be a slight voltage difference. This will cause one battery to try to charge the other slightly.
That would cause a small current flow unless one is completely dead, in which case the current might be fairly heavy.
But its not likely to show up on a multimeter unless you have it set on amps and in series with one of the batteries.
You might see a slight difference in the voltage of the system as the two equalize, but thats it.
If you are just trying to see if its working, then about the only way would be to switch on the solenoid using the aux battery, then carefully disconnect the original battery positive cable and see if the truck will crank.
BE CAREFUL with the original battery's positive cable!!! If you have done your work correctly, it will be hot and will short out and cause a fire if it touches a ground!!
DO NOT disconnect the original battery cable with the truck running. If your setup is not working, then you could quickly fry the alternator or the electronics in the engine.
If the truck cranks with that cable disconnected then it means the aux battery is in the system so it should be safe to run it.
BUT DO NOT turn the solenoid off while the engine is running!!
If the engine is running, and you have an amp gauge, then you will probably see an increase in the charging current when the second battery is switched in.
Other than that, about the only difference you might notice is a slightly faster starter if the original battery was a little weak.
Remember, you are going to have to have some way to charge the aux battery.
Do a search on dual batteries here, and you will see lots of different ways to have two batteries in a system.
I personally prefer my old truck's system with the split electrical system and the diode isolator, but I am quite willing to agree that some of the automatic solenoid systems are probably better for most setups.