Probably the rarest engine would be the all aluminum Z11 427 engine that was based on the 409 with a longer stroke crank. GM only made 50 cars with that engine and only 20 more engines for over the counter sale.
Oval Port.....
336781 , 454 , 1973-1985 , Open chamber
346236 , 454 , 1975-1978 , Open chamber ("peanut" ports)
353049 , 454 , 1970-1973 , Open chamber
3872702 , 396 and 427 , 1966 , Closed chamber
3904390 , 427 , 1966 , Closed chamber
904390 , 427 , 1966 , Closed chamber
3909802 , 396 and 427 , 1966-1967 , Closed chamber
3917215 , 396 and 427 , 1966-1969 , Closed chamber
3931063 , 396 and 427 , 1966-1969 , Closed chamber
3964280 , 427 and 454 , 1966-1970 , Closed chamber
3964290 , 427 and 454 , 1966-1970 , Closed chamber
3993820 , 402 and 454 , 1970-1971 , Open chamber
3999241 , 402 , 1970-1972 , Open chamber
6272292 , 402 and 454 , 1971 , Open chamber
Rectangle Port....
3856208 , 396 , 1965 , Closed chamber
3904391 , 396 and 427 , 1965-1967 , Closed chamber
3919840 , 396 and 427 , 1965-1969 , Closed chamber
3964291 , 396, 402, and 427 , 1965-1970 , Closed chamber
3964292 , 454 , 1970 , Closed chamber
3994025 , 454 , 1971 , Open chamber
3994026 , 454 , 1971 , Open chamber
3996074 , 454 , 1971 , Open chamber
6258723 , 454 , 1971 , Open chamber
6272990 , 454 , 1971 , Open chamber

The rarest big block chevy is this one
cast# CID years description
399204.....509.......70-71...4-bolt, Alum., CanAm, 4.5" bores, steel Cylinder liners
