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Sounds to me like the asbestos in side (honeycomb) is busting up... Have a buddy or wife stand behind the vehicle with a trash bag... Not directly behind it but off to the side... Or you do it and have them hold the gas to the floor for a second or pat it and rev the RPMS up and see if you have an chunks of stuff in the bag... Don't hold the bag tight around the exhaust or touch the pipe...... If so your cat is dieing... If not your cat could still be dieing..
If your truck is a "off road truck" just smash out the insides. an leave the case. Mine rotted off on its own. the funny thing is my 350 no egr or cat passed smog flying colors. If its the heat sheild get a hose clamp and go around the cat to keep the case together. Yes I am a major hack, but this is my plow truck