I'd avoid aluminum...
I've seen aluminum floor patches cause ten times more rot here..many people use aluminum roof flashing and pop rivets as a cheap and easy fix to get a vehicle decent looking enough to pass inspection here..but after a few months,and a salt bath during winter months,the aluminum VS steel creates a current,that causes electrolosis,and makes a battery of sorts..your floor looks like a white crystalline mess that is like battery acid,it eats the steel and aluminum,unless both are separated by some kind of insulator,like tar,plastic,etc..
One K5 I bought had all its floor rust patched that way,and it was a horror show --I had to cut it all out and do it right again!..Aluminum offers little structural strength also,even the diamond plate like running boards are made of is brittle..flex it a few times and it snaps like peanut brittle!..(and no,you cant weld aluminum to steel!)..
I'd use steel,galvanized lasts the longest,but is tricky to braze or weld without getting sick from the fumes the zinc makes when heated..I did my 74 K20 with 16 gauge galvanized sheet metal,,and used some garden fence posts that were "U" shaped for braces to stiffen the floors up-- its floors were still mint 15 years later when I scrapped it last May..only part of the truck that wasn't completely rotted away!..if only GM had galvanized the Blazers and all the other trucks from the factory!..
