Glow plugs must work to start a 6.2,even if its warm out,at least to get it going the first start of the day anyway...if your getting fuel to the cylinders and smoke at the tailpipe after cranking,its probably the glow plugs not getting things hot enough to fire off...sounds like your getting enough fuel..
See if 12V gets to the glow plugs with the key on--if it has been converted to a manual push button,hold the button on and use a test lamp to see if power is getting to the glow plug wires..
You can test the glow plugs by unplugging the wires from them and put a test lamp between the positive battery terminal and the glow plug terminal--the light should light up if its good..or you can remove them and hook jumper cables to the terminal and the hex portion and see if they turn red when you apply 12V..
Starting fluid should be avoided,but if you dare,you can try using some ,but do not activate the glow plugs before using any,disable them by taking the small wire off the glow plug relay so it cant energize them..its best to have someone crank the engine over at full tilt before spraying it in the intake--doing it alone by dumping some in the intake,then cranking it,usually results in problems,the starter drive or nose can suffer damage,and the engine will tend to bind and kick back ,which is hard on the rods and pistons..
I had to use ether to get my 6.2 started the first time,after that I worked the bugs out of the glow plugs and fuel system and its been OK since..I have had a few issues with rusty metal fuel lines letting air sneak in,I replaced them all with copper..also had a few rubber hoses crack at the hose clamps and let it get airbound also twice..