First, thank you for taking the time to school me on this, as this is something that I have not understood thus far. I've not even thought about it very much to this point. I do follow what you've said, but I still have some questions.
Glowing exhaust manifolds we have all seen also reach ~1200*, while manifolds EVENTUALLY crack and fail, they are exposed to "open air" and don't fail spectacularly because of the heat cycles. If heat cycles were an issue, headers alone would cause valve failure, as they shed heat far faster than a cast manifold.
Valves are in contact with cast iron or aluminum, which is the sink. Somewhere around 75% of the shed heat from valves, is through the head.
First of all, I've been thinking that the iron/aluminum head is what's causing the problem here. That the head, when up to temperature, cannot cool as quickly as the valve can. That when outside air, cold relative to the temperature of the head, is introduced, that this disparity in cooling (and shrinking) rates encourages warping in the valve as different parts cool at different rates, and the valve shrinks faster than its seat. That the convection of air is the problem, not any heat shed slowly via the manifold or anywhere else. That is what I have been thinking, and that is what directed my comment about summer temps vs. winter temps.
Second, I've never thought that valves (which can easily see >150,000 motion cycles per hour of runtime in addition to thermal stresses) were in the same category as manifolds, which typically see no motion cycles at all. I've thought that the valve is much more delicate than the plumbing downstream.
Removing an exhaust manifold (or installing headers) on the traditional small block, without correcting the AFR, WILL cause a lean condition because combustion efficiency has increased...more air in, but its up to a human to correct the fuel. Bad enough, that lean condition will lead to burned valves, pistons, etc.
Thirdly, when this (^^^^) happens, why does AFR change? Why is this increase any different from the increase that happens when the throttle is opened? More airflow should mean more fuel is mixed in, no?
See my first response to the OP's question...it was all in jest!
I actually missed the jesting, as I have heard several of those concerns from other sources. Clearly, I have much to learn about this...
