I'm assuming you already have the coils and Msd harness and 6ls to run all that, but the tbi needs a signal to know when to adjust fuel trims. You could probably rig something up to the 5.3 crank sensor, but you will also need the tbi computer and be able to tune it to read and interpret the crank signal. And do it correctly.
You're trying to go backwards and forwards at the same time. It's going to be more trouble than it's worth. Either slap a carb on it and run the 6ls and harness, or spend the few hundred bucks for the ls computer and wiring harness. PIck up a cheap ls1 intake and tb on ls1tech.com and run it.