This seems inherently wrong to me. Sure, it can be labeled, but the cost of a mistake could be very high, even deadly.
I do think that basic concept works with a garden sprayer, but it may not take long for gas to start eating parts.
Another idea is to put a tire valve stem into a gas can and pressurize it with a tire pump, garden sprayer, or regulated shop air. I have some plastic cans with valve stems in them for vents (no schrader) and the seal seems to work fine. You could even put an air regulator right on the can and have semi-regulated fuel pressure anywhere you have compressed air. Any guesses on whether a metal gas can is OK with 60psi?