Good luck with trying to get fuel without alcohol, even the places that say they don't usually do.

And the alcohol is just part of the issue. The bigger problem is the reformulation of fuel for modern cars, modern emission systems and modern emission standards while complying with EPA standards on which chemicals can even be used in fuel. Works great for injected cars but not so much for us old carb guys.
Do you have any fuel filters before the fuel pump??
Sounds like the problem is a fuel supply issue to the fuel pump, more than a carb issue. ANY restriction before the fuel pump WILL cause the fuel to boil in the fuel line before the pump. (remember when you put liquid in a vacuum you lower the boiling point) Check the sock in the tank, if it's looking sad replace it, if it looks dirty replace it. In the end you may end up putting an electric pump under the cab and eliminate the stock pump.
Venting out the gas cap is normal, the hotter it is the more it will vent and stink.
The only things that I've found that help with hot running loading up are:
1 use a phenolic or wood spacer under the carb to help insulate the heat.
2. mount a return style filter near the carb to help keep the fuel as cool as possible before it goes into the carb.
3. Get rid of the stock mechanical fuel pump/fuel heater.
All of these suggestions will help but will not fully fix hot weather fuel issues, fuel injection is the only real fix.