I have the CTS reading on the Holley and the Autometer gauge. The senders for both are located at the front of the intake before the thermostat. Technically the Autometer was giving me a higher reading once the motor got over 200F. So when I'm saying I would stop at 220F to cool off that was what the EFI told me and the Autometer was usually reading closer to 230F.
The Sniper EFI does not monitor knock. I did look and it was holding 40 degrees advanced during this time. I have not delved in to the tuning possibilities yet. I just downloaded the software and stopped there.So right now it just runs on the base tuning as well as the learned tuning the onboard software does for the first however many miles of driving.
I was curious what you were running for a fan on the 8.1L. I don't know if you remember the climb up 285 from 470, but it's pretty tough. Too bad you don't still live here so we could do a direct comparison. Obviously I was being passed by newer trucks pulling bigger campers as I sat on the side of the road cooling off, so it's not an issue for the newer trucks. The camper weighs about 4000lbs, so I try to remind myself between truck and camper and family and gear I'm probably hauling nearly 13,000lbs. Maybe I'm expecting too much from a factory 80's truck 454. I also had to pull Nick's truck up Kenosha Pass and it was heating up pretty quick doing that but it's a relatively short climb.
I think that will be the next step. I'm deciding between 2 options. Factory 6.2L mechanical fan (uses same fan clutch as 454) and shroud. I found I can get a 6.2L shroud from Classic Industries. My only concern is trail cooling. I was just reading @the_blaze thread and he's having idle cooling issues with the same mechanical fan and shroud.
The other option is 2 bigger electric fans on a shroud that covers the entire 19"x34" core. I have (2) 16" 2-speed Volvo fans I could try that with. Or I could go bigger and get (2) Derale 2-speed 17" diameter fans and max out the coverage. I'm kinda leaning this direction because I know it will still work on the trail.
If your AFR is 14:1 at higher loads/full throttle you're too lean. It needs to be down around 13:1 and even as low as 12.5:1 at full throttle. Add gas and it will probably cool down.
All the advice about making sure the cooling stack is sealed etc. are good too. An oil cooler isn't going to hurt but I also don't think you'll see it fix anything either. It might knock the time it takes to heat up back a bit, or the rate it cools off but I don't see it fixing the overheating. That said I would put one on.

So right now it just runs on the base tuning as well as the learned tuning the onboard software does for the first however many miles of driving.