I would suggest just loading up some thinner in the gun, and get used to your gun first. Just spray it into the air, it will have a "feel" for the trigger which is good to know...there is a point where you can only blow air, and when you pull the trigger a little more it will feed the liquid in the cup to the tip. Once you get a feel for that point, you can shoot the thinner through the gun to see what kind of pattern it has to it, and you can use that knowledge of pattern, and spray accordingly, knowing what your pattern looks like....its easy to see on the first color coat, but maybe not so easy to see on other coats, that is where that knowledge of your pattern will come in. I like to pull the trigger on the gun so it blows only air, before putting any paint through it, this will give the air a chance to stabilize before putting paint to the tip. Now here's where it really pays to shoot a spare panel, just hangin on the wall or something to get a feel for how much your putting on...keep about 10-12" from the surface, and keep the gun moving. Start outside of the panel, so your spraying off the surface, pull the trigger to get the air moving, but not liquid yet, then start moving the gun to the surface, and just before getting to the surface, pull the trigger fully and keep moving.
I think there is probably some videos on youtube showing someone painting something, check a few of those out, because if your like me, pictures (videos) are worth more than words sometimes.
Are you using an HVLP gun or siphon/gravity feed conventional gun? I just started using my first HVLP, and it puts a lot more paint on than my conventional siphon cup gun....
If you get into a run or sag, that is another realm of paintwork...lots of ways to repair the problem, of which I don't have a lot of experience doing. Take the little extra time to prep a spare panel (even a piece of 2x2 sheet metal) and then you know what your finished product will look like.
If you find yourself in a problem, you can stop where your at, and figure out whats going on, and how to rectify it, instead of it being on your truck.
In the end, you'll be amazed how much better a gun job w/2 part paint will be than a rattle can or a rustoleum job is.